|
|
isobutanol + NAD+ <=> H+ + Isobutyraldehyde + NADH
|
1.1.1.1
alcohol dehydrogenase
1.1.1.245
cyclohexanol dehydrogenase
|
–
–
|
|
BRENDA:
BS186845
MetaCyc:
RXN-7657
SABIO-RK:
9859
|
|
|
|
(R)-2,3-dihydroxy-3-methylbutanoate <=> 2-oxoisovalerate + H2O
|
4.2.1.9
dihydroxy-acid dehydratase
|
–
|
|
KEGG:
R04441
MetaCyc:
DIHYDROXYISOVALDEHYDRAT-RXN
|
|
|
|
H+ + pyruvate <=> (S)-2-Hydroxy-2-methyl-3-oxobutanoate + CO2
|
2.2.1.6
acetolactate synthase
4.1.1.1
pyruvate decarboxylase
|
–
–
|
|
BRENDA:
BR37100;
BS386675
KEGG:
R00006;
R00226
MetaCyc:
ACETOLACTSYN-RXN
SABIO-RK:
6473;
749
|
|
|
|
(R)-2,3-dihydroxy-3-methylbutanoate + NADP+ <=> (S)-2-Hydroxy-2-methyl-3-oxobutanoate + NADPH + H+
|
1.1.1.383
ketol-acid reductoisomerase [NAD(P)+]
1.1.1.86
ketol-acid reductoisomerase (NADP+)
|
–
–
|
|
BRENDA:
BR47598
KEGG:
R04439
MetaCyc:
ACETOLACTREDUCTOISOM-RXN;
RXN-16061
SABIO-RK:
4125
|
|
|
|
2-oxoisovalerate + H+ <=> Isobutyraldehyde + CO2
|
2.2.1.6
acetolactate synthase
4.1.1.1
pyruvate decarboxylase
4.1.1.7
benzoylformate decarboxylase
4.1.1.72
branched-chain-2-oxoacid decarboxylase
|
–
–
–
–
|
|
BRENDA:
BS363283
MetaCyc:
RXN-7643
|
|